TITLE

Alkenylation of arylamines and N-arylacetamides with acetylene compounds in superacids

AUTHOR(S)
Shchukin, A.; Vasil�ev, A.; Aristov, S.; Fukin, G.; Rudenko, A.
PUB. DATE
July 2008
SOURCE
Russian Journal of Organic Chemistry;Jul2008, Vol. 44 Issue 7, p965
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Vinyl type cations generated in superacid HSO3F by the protonation of the triple bond of acetylene compounds efficiently react with arylammonium ions and N-arylacetamides yielding alkenylation products of the aromatic rings in the given amino derivatives. The regio-and stereoselectivity of electrophilic aromatic substitution was investigated involving vinyl type cations and arylammonium ions or N-arylacetamides in HSO3F.
ACCESSION #
33636090

 

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